|
|
(3R)-2''-hydroxydihydrodaidzein + NADP+ <=> 2''-hydroxydaidzein + NADPH + H+
|
1.3.1.51
2'-hydroxydaidzein reductase
|
–
|
|
BRENDA:
BR1199
KEGG:
R03962
MetaCyc:
RXN-4502
|
|
|
|
(3R,4R)-7,2,4''-trihydroxyisoflavanol + NADP+ <=> (3R)-2''-hydroxydihydrodaidzein + NADPH + H+
|
1.1.1.348
(3R)-2'-hydroxyisoflavanone reductase
|
–
|
|
MetaCyc:
RXN-4504
|
|
|
|
demethylmedicarpin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> (6aS,11aS)-3,6a,9-trihydroxypterocarpan + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.93
3,9-dihydroxypterocarpan 6a-monooxygenase
|
–
|
|
MetaCyc:
RXN-4505
|
|
|
|
daidzein + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 2''-hydroxydaidzein + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.90
isoflavone 2'-hydroxylase
|
–
|
|
MetaCyc:
RXN-4501
|
|
|
|
(3R,4R)-7,2,4''-trihydroxyisoflavanol <=> demethylmedicarpin + H2O
|
4.2.1.139
pterocarpan synthase
|
–
|
|
MetaCyc:
RXN-13699
|
|